You can specify the assembler (and the C compiler as well) at ./configure time by setting the AS and CC variables. See ./configure --help for the details.
gcc-11_4 Meta-port for the default version of the GNU Compiler Collection
gcc10-10.3.0 GNU Compiler Collection 10
gcc11-11.2.0 GNU Compiler Collection 11
gcc6-aux-20180516_2,1 Version of GCC 6 with full Ada support
gcc8-8.5.0_1 GNU Compiler Collection 8
gcc9-9.4.0 GNU Compiler Collection 9
llvm-13 Meta-port for the default version of the LLVM Toolchain
llvm10-10.0.1_8 LLVM and Clang
llvm11-11.0.1_3 LLVM and Clang
llvm12-12.0.1_6 LLVM and Clang
llvm13-13.0.0_2 LLVM and Clang
llvm70-7.0.1_6 LLVM and Clang
llvm80-8.0.1_5 LLVM and Clang
llvm90-9.0.1_3 LLVM and Clang